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C06 — Molecular photoisomerization within 2D materials

Principal Investigator: Prof. Stefan Hecht, Ph.D.

Located at: Humboldt-Universität zu Berlin

Project C06 explores molecular photochromism within TMDs, graphene, and nanotubes to understand and control the optoelectronic properties of hybrid materials. Using diarylethenes with large FMO shifts it aims to influence excitonic insulator phase transitions in TiSe2 and TaNiSe5, while the photoswitching behavior of dihydropyrenes and spiropyrans with large dipole changes will be controlled by strong external electric fields.

Experimental methods: organic synthesis of photoswitches, nuclear magnetic resonance (NMR), mass spectrometry, thermal gravimetric analysis (TGA), absorption (UV/vis)